Посмотрите функции:
BuildCommDCB BuildCommDCBAndTimeouts ClearCommBreak ClearCommError CommConfigDialog EscapeCommFunction GetCommConfig GetCommMask GetCommModemStatus GetCommProperties GetCommState GetCommTimeouts GetDefaultCommConfig PurgeComm SetCommBreak SetCommConfig SetCommMask SetCommState SetCommTimeouts SetDefaultCommConfig SetupComm TransmitCommChar WaitCommEvent